| Alvin Community College Child Development Laboratory School | 3110 Mustang RD, Alvin, TX 77511 | Preschool |
| Alvin FUMC Preschool | 611 W S ST, Alvin, TX 77511 | Preschool |
| Alvin Head Start | 1019 E House ST, Alvin, TX 77511 | Preschool |
| Alvin Head Start Mark Twain Elementary | 610 East Clemens, Alvin, TX 77511 | Preschool |
| Alvin ISD DC | 907 Cedar Lawn, Alvin, TX 77511 | Preschool |
| First Steps Early Learning & Montessori Center | 600 Avenue E 1/2, Alvin, TX 77511 | Preschool |
| Good Seeds Daycare | 2541 Hwy 35 Bypass, Alvin, TX 77511 | Preschool |
| Granny B's Child Development Center | 1305 Davis Bend Rd, Alvin, TX 77511 | Preschool |
| Hand In Hand CD | 1012 E House St, Alvin, TX 77511 | Preschool |
| Happy Start ~ Kid Connection Academy | 2280 S BYPASS 35, Alvin, TX 77511 | Center |
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| Happy Trails Child Care | 1610 S Gordon Street, Alvin, TX 77511 | Preschool |
| Heritage Christian DCC | 315 W House, Alvin, TX 77511 | Preschool |
| Kandiland Day Care | 2280 By Pass 35, Alvin, TX 77511 | Preschool |
| Liberty Christian Preschool | 2525 W Dumble, Alvin, TX 77511 | Preschool |
| Ms Susans Christian Child Care Center | 851 Dilling St, Alvin, TX 77511 | Preschool |
| Precious Stones Preschool | 1407 Victory Ln, Alvin, TX 77511 | Preschool |
| Shepherds Heart Preschool | 831 Fm 2917, Alvin, TX 77511 | Preschool |
| Sunshine Childrens Academy | 1475 E S St, Alvin, TX 77511 | Preschool |
| The Village Early Learning Center | 614 South Jackson St, Alvin, TX 77511 | Preschool |
| YMCA at Hood Case Elementary | 1450 Heights Rd, Alvin, TX 77511 | Center |